96332-66-0Relevant academic research and scientific papers
CYCLOADDITIONS OF DISUBSTITUTED DIAZO COMPOUNDS TO P-CHLORO(BISTRIMETHYLSILYL) METHYLENE PHOSPHINE.
Thoraval, J. Y.,Nagai, W.,Yeung Lam Ko, Y. Y. C.,Carrie, R.
, p. 3859 - 3868 (2007/10/02)
Disubstituted diazo compounds rapidly add to P-chloro (bistrimethylsilyl) methylene phosphine at low temperature. 1H, 31P and 13C NMR allow the characterization of the resulting cycloadducts and the establisment of the stereochemistry of the resulting cycloadducts which are potential precursors of ?3λ5 bis methylene phosphorane by nitrogen extrusion.
4? + 2? Cycloadditions to P-Chlorobis(trimethylsilyl)methylenephosphine: New Cyclic Compounds with a >C=P-Double Bond
Ko, Yeung Y. C. Yeung Lam,Carrie, Robert
, p. 1640 - 1641 (2007/10/02)
The reaction of P-chlorobis(trimethylsilyl)methylenephosphine with several 1,3-dipoles and two dienes gives cycloadducts regiospecifically, these will eliminate Me3SiCl at low temperatures if the resulting compound is of an 'aromatic' type, leading to new cyclic >C=P- double bond derivatives.
