96354-48-2Relevant academic research and scientific papers
Stereoselectivity in the Reactions between the Anion of 4-Phenyl-5,6-dihydro-2H-thiopyran 1-Oxide and Electrophiles
Crumbie, Robyn L.,Ridley, Damon D.,Steel, Peter J.
, p. 119 - 132 (2007/10/02)
Treatment of the anion (17), prepared from the six-membered ring allylic sulfoxide 4-phenyl-5,6-dihydro-2H-thiopyran 1-oxide (8) with primary alkyl halides at -78 deg C, affords trans-2-alkyl-4-phenyl-5,6-dihydro-2H-thiopyran 1-oxides exclusively.The ster
