96429-71-9

Basic information

• Product Name: 1,2-di-O-benzyl-3-O-triphenylmethyl-sn-glycerol
• Synonyms: 1,2-di-O-benzyl-3-O-triphenylmethyl-sn-glycerol
• CAS NO: 96429-71-9
• Molecular Weight: 514.664
• Mol File: 96429-71-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2-di-O-benzyl-3-O-triphenylmethyl-sn-glycerol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-di-O-benzyl-3-O-triphenylmethyl-sn-glycerol(96429-71-9)
• EPA Substance Registry System: 1,2-di-O-benzyl-3-O-triphenylmethyl-sn-glycerol(96429-71-9)

Safety Data

• Hazardous Substances Data: 96429-71-9(Hazardous Substances Data)

Upstream product

• 16495-03-7 (S)-4-(benzyloxymethyl)-2,2-dimethyl-1,3-dioxolane 
• 100-44-7 benzyl chloride 
• 76-83-5 trityl chloride 
• 56552-80-8 (R)-3-benzyloxy-1,2-propanediol 
• 20196-71-8 (2S)-2,3-bis(benzyloxy)propanol 
• 83526-68-5 (S)-1-(benzyloxy)-3-trityloxypropan-2-ol 

Downstream Products

• 96429-74-2 (S)-9-<<2,3-bis(benzyloxy)-1-propoxy>methyl>guanine 
• 96429-73-1 1-O-(chloromethyl)-2,3-di-O-benzyl-L-glycerol 
• 58530-76-0 (R)-2,3-dibenzyloxy-1-propanol 

Relevant articles and documents

Enhanced reactivity of secondary hydroxyl groups in the O-alkylation of carbohydrate-related primary-secondary vic-glycols. Regioselective 2-O-benzylation of 1,3:2,4-di-O-ethylidene-D-glucitol

Partial O-alkylation of 1,3:2,4-di-O-ethylidene-D-glucitol (1a), 1,2-O-isopropylidene-3-O-methyl-α-D-glucofuranose (1b), and R-(+)-1-O-benzylglycerol (1c) with benzyl chloride in a KOH/DMSO system results in products of monoalkylation at the secondary (4a-c) and at the primary hydroxyl (2a-c) in ratios of over 95:5 (a), ca. 2:1 (b), and ca. 1:1 (c), whereas (+/-)propane-1,2-diol (1d) gives only the product of 1-O-benzylation (2d).A qualitatively similar result is observed upon O-alkylation of diols (1a-e) with 2-methoxyethanol tosylate.

LILIOSIDE C, A GLYCEROL GLUCOSIDE FROM LILIUM LANCIFOLIUM

A new glycerol glucoside, lilioside C, has been isolated from the leaves and stems of Lilium lancifolium.Its structure including the configuration of the aglycone moiety has been elucidated by chemical and spectroscopic means and by its synthesis.Key Word Index - Lilium lancifolium; Liliaceae; tiger lily; glycerol glucoside; 3-O-β-D-glucopyranosyl-sn-glycerol; lilioside C; stereochemistry; synthesis.