96460-69-4

Basic information

• Product Name: 1-phenoxy-4-thiocyanatobenzene
• Synonyms: 1-phenoxy-4-thiocyanatobenzene
• CAS NO: 96460-69-4
• Molecular Weight: 227.287
• Mol File: 96460-69-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-phenoxy-4-thiocyanatobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenoxy-4-thiocyanatobenzene(96460-69-4)
• EPA Substance Registry System: 1-phenoxy-4-thiocyanatobenzene(96460-69-4)

Safety Data

• Hazardous Substances Data: 96460-69-4(Hazardous Substances Data)

Upstream product

• 1187951-62-7 potassium trifluoro(4-phenoxyphenyl)borate 
• 1147550-11-5 ammonium thiocyanate 
• 51067-38-0 4-phenoxyphenylboronic acid 
• 1111-67-7 copper(I) thiocyanate 
• 540-72-7 sodium thiocyanide 
• 139-59-3 4-phenoxyanilin 
• 333-20-0 potassium thioacyanate 

Downstream Products

• 1333415-80-7 1-phenoxy-4-[(trifluoromethyl)sulfanyl]benzene 

Relevant articles and documents

Electrochemical ipso-Thiocyanation of Arylboron Compounds

An operationally simple electrochemical method for the transition-metal-free ipso-thiocyanation of arylboronic acids and aryl trifluoroborates has been developed. The SCN electrophile is generated in situ by anodic oxidation of thiocyanate anions, which avoids formation of salt waste and prevents unwanted side reactions arising from chemical oxidants. The reaction proceeds regiospecifically, and the scope extends to non-activated aromatic systems. (Figure presented.).

Transition-metal-free synthesis of thiocyanato- or nitro-arenes through diaryliodonium salts

A transition-metal-free approach to facile synthesis of thiocyanato- and nitro-arenes was developed from KSCN (potassiumthiocyanate) or NaNO2with diaryliodonium salts in good yields under mild conditions. The reaction was compatible with a variety of sensitive functional substituents such as halides and nitro and ester groups. The usefulness of arylation products has been realized. (Formula Present).