965-16-2Relevant academic research and scientific papers
Organotin Biocides. XIII. C-Triorganostannylimidazoles, -benzoxazoles and -benzothiazoles
Molloy, Kieran C.,Waterfield, Philip C.,Mahon, Mary F.
, p. 61 - 74 (2007/10/02)
The synthesis, spectroscopic characterisation, and reactivity of a series of triorganotin imidazoles, benzothiazoles and benzoxazoles R3Sn(Het) (R=Me, Bu, Ph) are described.The structure of 2-(triphenylstannyl)benzothiazole has been determined by crystallographic methods.Space group: Triclinic, P1; a 9.501(1), b 10.172(2), c 13.231(2) Angstroem, β 70.46(1), γ 69.71(1) deg, U 1082.8 Angstroem3, F(000)=484, μ(Mo-Kα) 11.74 cm-1, R=0.0719 for 2264 reflections with I>3?I.The geometry at the tin is tetrahedral.Bond angles at tin are used to discuss the reactivity and Moessbauer spectra of these species.
