96530-30-2Relevant academic research and scientific papers
γ-ALKYLATION OF α,β-UNSATURATED KETONES: α'-PHENYLSULFONYL GROUPS AS REGIOSELECTIVE CONTROL ELEMENTS
Lansbury, Peter T.,Bebernitz, Gregory E.,Maynard, Susan C.,Spagnuolo, Ciro J.
, p. 169 - 172 (2007/10/02)
The α'-phenylsulfonyl derivative of E-3-penten-2-one (3) undergoes predominant γ-alkylation with a variety of alkyl iodides when first converted into a trilithiated intermediate with excess lithium diisopropylamide in tetrahydrofuran-hexane.
