96558-50-8Relevant articles and documents
Iron-catalyzed alkylations of aromatic Grignard reagents
Cahiez, Gerard,Habiak, Vanessa,Duplais, Christophe,Moyeux, Alban
, p. 4364 - 4366 (2007)
(Chemical Equation Presented) Any old iron: Two efficient iron-catalyzed cross-coupling reactions between aryl Grignard reagents and alkyl bromides were developed that are suitable for large-scale applications. The first procedure uses iron acetylacetonate and involves a cooperative effect between the two ligands N,N,N′,N′-tetramethylethylenediamine (TMEDA) and hexamethylenetetraamine (HMTA), while the second procedure uses [(FeCl 3)2(tmeda)3] as catalyst. 2007 Wiley-VCH Verlag GmbH & Co. KGaA.