96569-80-1Relevant articles and documents
Acid catalyzed rearrangement of vinyl and ketene acetals
Maziarz, Elzbieta,Furman, Bart?omiej
, p. 1651 - 1658 (2014/02/14)
Substituted vinyl and ketene acetals undergo smooth oxygen-to-carbon rearrangement with a catalytic amount of TMSOTf to afford chain-extended ketones or esters, respectively. The developed procedure has been applied to the stereoselective synthesis of C-glycosides from the corresponding anomeric vinyl ethers.
HETEROATOM DIRECTED Β-LITHIATION OF A VINYL ETHER
McDougal, Patrick G.,Rico, Joseph G.
, p. 5977 - 5980 (2007/10/02)
Oxygen directed β-deprotonation of a vinyl ether leads to Z substituted enol ethers.The stereoselective elaboration to a naturally occuring threo 1,3-diol is described.