96569-80-1

Basic information

• Product Name: Benzene, [1-(methoxymethoxy)ethenyl]-
• CAS NO: 96569-80-1
• Molecular Formula: C10H12O2
• Molecular Weight: 164.204
• Mol File: 96569-80-1.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [1-(methoxymethoxy)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-(methoxymethoxy)ethenyl]-(96569-80-1)
• EPA Substance Registry System: Benzene, [1-(methoxymethoxy)ethenyl]-(96569-80-1)

Safety Data

• Hazardous Substances Data: 96569-80-1(Hazardous Substances Data)

Upstream product

• 109-87-5 Dimethoxymethane 
• 4358-87-6 (RS)-methyl mandelate 
• 65-85-0 benzoic acid 
• 54354-04-0 benzoic acid methoxymethyl ester 

Downstream Products

• 96569-83-4 hydrocinnamaldehyde 
• 96569-87-8 ((Z)-1-Methoxymethoxy-hept-1-enyl)-benzene 
• 96569-84-5 1-((Z)-2-Methoxymethoxy-2-phenyl-vinyl)-cyclohexanol 
• 96569-82-3 (Z)-3-Methoxymethoxy-1,3-diphenyl-prop-2-en-1-ol 
• 96569-85-6 1-((Z)-2-Methoxymethoxy-2-phenyl-vinyl)-cyclopentanol 
• 96569-86-7 (Z)-1-Methoxymethoxy-3-methyl-1-phenyl-non-1-en-3-ol 
• 96569-81-2 ((Z)-1-methoxymethoxypropenyl)-benzene 
• 5650-40-8 2-hydroxypropiophenone 
• 61952-19-0 (+)-threo-1,5-diphenylpentane-1,3-diol 
• 109007-67-2 (-)-erythro-1,5-diphenylpentane-1,3-diol 
• 96569-92-5 (S)-4-Phenethyl-6-phenyl-[1,3]dioxane 
• 96569-92-5 C₁₈H₂₀O₂ 
• 96569-88-9 (1R,3S)-1-Methoxymethoxy-1,5-diphenyl-pentan-3-ol 
• 96569-88-9 (1S,3S)-1-Methoxymethoxy-1,5-diphenyl-pentan-3-ol 

Relevant articles and documents

Acid catalyzed rearrangement of vinyl and ketene acetals

Substituted vinyl and ketene acetals undergo smooth oxygen-to-carbon rearrangement with a catalytic amount of TMSOTf to afford chain-extended ketones or esters, respectively. The developed procedure has been applied to the stereoselective synthesis of C-glycosides from the corresponding anomeric vinyl ethers.

HETEROATOM DIRECTED Β-LITHIATION OF A VINYL ETHER

Oxygen directed β-deprotonation of a vinyl ether leads to Z substituted enol ethers.The stereoselective elaboration to a naturally occuring threo 1,3-diol is described.