96667-35-5

Upstream product

• 86537-31-7 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 
• 6510-91-4 5-(phenylthio)pentan-2-ol 

Downstream Products

• 96667-79-7 1-(1-Benzenesulfonyl-2-methyl-cyclobutyl)-3-methyl-butan-1-ol 
• 96667-78-6 Acetic acid 1-(1-benzenesulfonyl-2-methyl-cyclobutyl)-3-methyl-butyl ester 
• 96667-77-5 ((1R,2R)-1-Benzenesulfonyl-2-methyl-cyclobutyl)-methanol 

Relevant academic research and scientific papers

Applications of highly enantioenriched alcohols bearing a phenylthio group in the preparation of ring compounds. The two-pot synthesis of an enantiopure spiroacetal pheromone bearing three chiral centers

The new chiron (S)-6-phenylthio-2-hexanol (3) was prepared in high enantiomeric excess by baker's yeast reduction of the corresponding ketone. Enantioenriched alcohols 1, 2 and 3, prepared previously by a similar procedure, or their racemic counterparts, were transformed into ring closed compounds 5-methyl-2-(phenylthio)tetrahydrofuran (9), 6-methyl-2- (phenylthio)tetrahydropyran (10), 2-methyl-1-phenylsulfonyl cyclopropane (14), cyclobutane (15), cyclopentane (16), and a bee pheromone, (2S,6R,8S)- 2,8-dimethyl-1,7-dioxaspiro[5.5]undecane (20).

Bridgehead Reactivity, Nucleophilic and Radical Additions, and Lithium Aluminum Hydride Reduction of 1-(Arylsulfonyl)bicyclobutanes: General Access to Substituted, Functionalized Cyclobutanes. Syntheses of (+/-)-Citrilol Acetate, (+/-)-Junionone, and the

A general approach to the synthesis of a wide range of substituted cyclobutane derivatives is based on two specific reactions of 1-(arylsulfonyl)bicyclobutanes (1) and on some general reactions of the bicyclobutane ring systems.One specific cyclobutane fo