86537-31-7

Basic information

• Product Name: 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane
• CAS NO: 86537-31-7
• Molecular Weight: 208.281
• Mol File: 86537-31-7.mol

Chemical Properties

• CAS DataBase Reference: 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane(86537-31-7)
• EPA Substance Registry System: 2-exo-methyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane(86537-31-7)

Safety Data

• Hazardous Substances Data: 86537-31-7(Hazardous Substances Data)

Upstream product

• 124292-06-4 2-(2-Benzenesulfonyl-1-methyl-ethyl)-oxirane 
• 96689-19-9 [(3-pentenyl)sulfonyl]benzene 
• 60788-43-4 1-(phenylsulfonyl)-trans-3,4-epoxypentane 
• 60788-43-4 5-phenylsulfonyl-2,3-epoxypentane 
• 96745-06-1 trans-1-<(1SR)-1-<(methylsulfonyl)oxy>ethyl>-(2SR)-2-(phenylsulfonyl)cyclopropane 

Downstream Products

• 86537-46-4 (2-Methyl-cyclobutanesulfonyl)-benzene 
• 124291-97-0 ((1S,2S,4R,5S)-1-Benzenesulfonyl-4-tert-butyl-5-methyl-bicyclo[2.1.1]hex-2-yl)-methanol 
• 124291-97-0 ((1S,2R,4R,5S)-1-Benzenesulfonyl-4-tert-butyl-5-methyl-bicyclo[2.1.1]hex-2-yl)-methanol 
• 124291-98-1 2-((1R,2S,4R,5R)-1-Benzenesulfonyl-5-methyl-bicyclo[2.1.1]hex-2-yl)-propan-2-ol 
• 124291-98-1 2-((1R,2R,4R,5R)-1-Benzenesulfonyl-5-methyl-bicyclo[2.1.1]hex-2-yl)-propan-2-ol 
• 117487-84-0 ((1S,2S,3S)-3-Benzenesulfonyl-2-methyl-bicyclo[1.1.0]but-1-yl)-piperidin-1-yl-methanone 
• 117487-86-2 2-((1R,2R,3R)-3-Benzenesulfonyl-2-methyl-bicyclo[1.1.0]but-1-ylmethoxy)-tetrahydro-pyran 
• 124291-91-4 3-((1R,2R,3R)-3-Benzenesulfonyl-2-methyl-cyclobutylmethyl)-2,2-dimethyl-oxirane 
• 124291-90-3 2-((1S,2R,3R)-3-Benzenesulfonyl-1-tert-butyl-2-methyl-cyclobutylmethyl)-oxirane 
• 124291-47-0 (1R,2S,3S)-3-Benzenesulfonyl-2-methyl-bicyclo[1.1.0]butyryl chloride 
• 124291-84-5 [(1R,2R,3R)-2-Methyl-3-(3-methyl-but-2-enyl)-cyclobutanesulfonyl]-benzene 
• 124320-94-1 ((1S,2S,3R)-3-Allyl-3-tert-butyl-2-methyl-cyclobutanesulfonyl)-benzene 
• 96745-09-4 r-2-methyl-c-3-methyl-t-1-(phenylsulfonyl)cyclobutane 
• 96745-10-7 r-2-methyl-c,c-1,3-dimethyl-1-(phenylsulfonyl)cyclobutane 

Relevant articles and documents

NEW BRIDGEHEAD-SUBSTITUTED 1-(ARYLSULFONYL)BICYCLOBUTANES AND SOME NOVEL ADDITION REACTIONS OF THE BICYCLIC SYSTEM

In view of planned syntheses of target cyclobutane derivatives, a series of new 3-substituted bicyclobutanes was prepared from sulfones 1-7.Some novel addition reactions involving the central bond were then applied to several of the new compounds as well

Stereochemistry of Addition of Organocopper Reagents and of the Hydride Ion to 1-(Arylsulfonyl)bicyclobutanes

Addition of methylmagnesium iodide/cuprous iodide or of lithium dimethylcuprate to 2-exo- and 2-endo-methyl-1-(phenylsulfonyl)bicyclobutane and determination of the relative geometry of the methyls in the 2,3-dimethylcyclobutanes obtained allowed u