96689-19-9

Upstream product

• 4784-77-4 (E)-1-Bromo-2-butene 
• 3112-85-4 methylphenylsulfonate 
• 3406-02-8 bis(phenylsulfonyl)methane 
• 107735-50-2 trans-5,5-bis(phenylsulfonyl)-2-pentene 

Downstream Products

• 107735-56-8 1-tetrahydropyranyloxy-8 benzenesulfonyl-10E-dodecene 
• 60788-43-4 1-(phenylsulfonyl)-trans-3,4-epoxypentane 
• 119475-52-4 2-(N-acetyl-N-phenylamino)-3-benzenesulfonyl-5-ethylthiophene 
• 107735-59-1 (E)-8-Benzenesulfonyl-dodec-10-en-1-ol 
• 33956-49-9 (8E,10E)-dodeca-8,10-dienol 
• 109628-63-9 Acetic acid 1-((E)-1-benzenesulfonyl-pent-3-enyl)-heptyl ester 
• 109628-63-9 Acetic acid 1-((Z)-1-benzenesulfonyl-pent-3-enyl)-heptyl ester 
• 109628-64-0 EE 4-benzenesufonyl 2,5-dodecadiene 
• 109628-65-1 [((2E,5Z)-Dodeca-2,5-diene)-5-sulfonyl]-benzene 
• 96745-06-1 trans-1-<(1SR)-1-<(methylsulfonyl)oxy>ethyl>-(2SR)-2-(phenylsulfonyl)cyclopropane 
• 96667-68-4 r-2-methyl-t-3-methyl-t-1-(phenylsulfonyl)cyclobutane 
• 96745-09-4 r-2-methyl-c-3-methyl-t-1-(phenylsulfonyl)cyclobutane 
• 96745-10-7 r-2-methyl-c,c-1,3-dimethyl-1-(phenylsulfonyl)cyclobutane 
• 96667-24-2 2-exo,3-dimethyl-1-(phenylsulfonyl)bicyclo<1.1.0>butane 

Relevant academic research and scientific papers

IODINE-INDUCED IMINOTHIOLACTONIZATION OF γ,δ-UNSATURATED SECONDARY THIOAMIDES, NEW ENTRY TO 2-ACETOAMIDOTHIOPHENES

Iodine-induced cyclization of γ,δ-unsaturated secondary thioamides 1 proceeded regio- (5-exo-trigonal) and chemo- (sulfur-carbon bond formation)selectively, providing iminothiolactones 2, which were converted in two-step sequences (dehydroiodination and N-acetylation) into 2-acetoamidothiophenes 4.This procedure was performed in one flask to afford polysubstituted 2-aminothiophenes.

SYNTHESIS WITH SULFONES XLIV. STEREOSELECTIVE PREPARATION OF EE 1,3-DIENES BY ELIMINATION OF BENZENESULFINIC ACID FROM E HOMOALLYLIC SULFONES.

The preparation of pure E and Z homoallylic 1,1-disulfones followed by the stereoselective reduction of one sulfonyl moiety afforded pure E and Z homoallylic sulfones respectively.Basic elimination with tBuOK in THF gave the corresponding 1,3-dienes in good yield.This reaction, highly stereoselective in the case of E homoallylic sulfones, has been used in the synthesis of (8E,10E) 8,10-dodecadienol, 10 and (9E)9,11-dodecadienol, 15, insect pheromone components.