96717-54-3

Upstream product

• 88791-99-5 (E)-3-Methyl-4-{(2S,3S,4R,5S)-5-[(2S,3S)-3-((1R,2S)-1-methyl-2-trimethylsilanyloxy-propyl)-oxiranylmethyl]-3,4-bis-trimethylsilanyloxy-tetrahydro-pyran-2-yl}-but-2-enoic acid methyl ester 
• 66262-52-0 methyl monate A 
• 96717-45-2 Lithium; (Z)-1-methoxy-3-{(2S,3S,4R,5S)-5-[(2S,3S)-3-((1R,2S)-1-methyl-2-trimethylsilanyloxy-propyl)-oxiranylmethyl]-3,4-bis-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl}-buta-1,3-dien-1-olate 
• 96717-53-2 6-(4-Methoxy-phenyl)-4-{(2S,3S,4R,5S)-5-[(2S,3S)-3-((1R,2S)-1-methyl-2-trimethylsilanyloxy-propyl)-oxiranylmethyl]-3,4-bis-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl}-5,6-dihydro-pyran-2-one 

Relevant academic research and scientific papers

The Chemistry of Pseudomonic Acid. Part 8. Electrophilic Substitutions at C-2 and C-15 of the Pseudomonic Acid Nucleus by Means of Lithium Dienolates

The regiochemistry of substitutions at C-2 (α) and C-15 (γ) of lithium dienolates (2) derived from esters of monic acid (1d) depends on the nature of the electrophile.Substitution at C-2 affords diastereoisomeric mixtures of the deconjugated esters (3).Th