96717-53-2Relevant academic research and scientific papers
The Chemistry of Pseudomonic Acid. Part 8. Electrophilic Substitutions at C-2 and C-15 of the Pseudomonic Acid Nucleus by Means of Lithium Dienolates
Crimmin, Michael J.,O'Hanlon, Peter J.,Rogers, Norman H.
, p. 549 - 556 (2007/10/02)
The regiochemistry of substitutions at C-2 (α) and C-15 (γ) of lithium dienolates (2) derived from esters of monic acid (1d) depends on the nature of the electrophile.Substitution at C-2 affords diastereoisomeric mixtures of the deconjugated esters (3).Th
