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Photon-Induced Reactions: Part V - Photochemical and Chemical Oxidation Products of Dillapiole and Isodillapiole
Walia, S.,Dureja, P.,Mukerjee, S. K.
, p. 147 - 150 (2007/10/02)
Several photometabolites of dillapiole (1), obtained by irradiating it in methanol have been identified as isodillapiole (2), dihydrodillapiole (3), 1-cyclopropyl-2,3-dimethoxy-4,5-methylenedioxybenzene (4), dillaldehyde (7) and two new methanol adducts (5) and (6).Isodillapiole (2) under the same conditions furnishes 5, 6 and 7.Dye-sensitized photooxidation of 1 gives, besides the aldehydes 7 and 8, dihydroxydillapiole (11).For comparison, KMnO4 oxidation of 1 has also been investigated in detail.
