17672-89-8

Basic information

• Product Name: 4,5-Dimethoxy-6-[(E)-1-propenyl]-1,3-benzodioxole
• Synonyms: 4,5-Dimethoxy-6-[(E)-1-propenyl]-1,3-benzodioxole;Isodillapiole
• CAS NO: 17672-89-8
• Molecular Formula: C₁₂H₁₄O₄
• Molecular Weight: 222.24
• Mol File: 17672-89-8.mol
• Article Data: 3

Chemical Properties

• Melting Point: 44 °C(Solv: ligroine (8032-32-4))
• Boiling Point: 303.5±0.0 °C(Predicted)
• Appearance: /
• Density: 1.172±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 4,5-Dimethoxy-6-[(E)-1-propenyl]-1,3-benzodioxole(CAS DataBase Reference)
• NIST Chemistry Reference: 4,5-Dimethoxy-6-[(E)-1-propenyl]-1,3-benzodioxole(17672-89-8)
• EPA Substance Registry System: 4,5-Dimethoxy-6-[(E)-1-propenyl]-1,3-benzodioxole(17672-89-8)

Safety Data

• Hazardous Substances Data: 17672-89-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 484-31-1 dillapiole 

Downstream Products

• 936083-47-5 4-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-5-methyl-3-(2,4,6-trimethylphenyl)-4,5-dihydroisoxazole 
• 1133322-60-7 5-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-4-methyl-3-(2,4,6-trimethylphenyl)-4,5-dihydroisoxazole 
• 1133322-54-9 3-(4-methoxyphenyl)-5-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-4-methyl-4,5-dihydroisoxazole 
• 1133322-55-0 3-(4-methoxyphenyl)-4-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-5-methyl-4,5-dihydroisoxazole 
• 96573-28-3 2,3-dimethoxysesamyl γ,γ-dimethylallylether 
• 96573-18-1 2,3-dimethoxysesamyl n-hexylether 
• 96573-23-8 2,3-dimethoxysesamyl β-cyanoethylether 
• 96573-22-7 2,3-dimethoxysesamyl β-methallylether 
• 96573-27-2 2,3-dimethoxysesamyl n-propylether 
• 96573-20-5 6-allyloxy-4,5-dimethoxy-1,3-benzodioxole 
• 38971-74-3 Dillapional 
• 23731-65-9 2,3-dimethoxy-4,5-methylenedioxybenzaldehyde 
• 87687-11-4 dihydroxyisodillapiole 
• 96753-96-7 1-(2,3-dimethoxy-4,5-methylenedioxyphenyl)but-1-en-3-one 

Relevant articles and documents

A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds

A polymer-supported iridium catalyst has been prepared and used in the isomerisation of the double bonds in aryl allylic derivatives with excellent trans selectivity and without the need for conventional work-up procedures.

Photon-Induced Reactions: Part V - Photochemical and Chemical Oxidation Products of Dillapiole and Isodillapiole

Several photometabolites of dillapiole (1), obtained by irradiating it in methanol have been identified as isodillapiole (2), dihydrodillapiole (3), 1-cyclopropyl-2,3-dimethoxy-4,5-methylenedioxybenzene (4), dillaldehyde (7) and two new methanol adducts (5) and (6).Isodillapiole (2) under the same conditions furnishes 5, 6 and 7.Dye-sensitized photooxidation of 1 gives, besides the aldehydes 7 and 8, dihydroxydillapiole (11).For comparison, KMnO4 oxidation of 1 has also been investigated in detail.