17672-89-8

Upstream product

• 484-31-1 dillapiole 
• 67-56-1 methanol 

Downstream Products

• 23731-65-9 2,3-dimethoxy-4,5-methylenedioxybenzaldehyde 
• 69232-77-5 4,5-Dimethoxy-6-(1-methoxy-propyl)-benzo[1,3]dioxole 
• 69232-78-6 4,5-Dimethoxy-6-(2-methoxy-propyl)-benzo[1,3]dioxole 
• 22027-56-1 dillapionic acid 
• 87687-11-4 dihydroxyisodillapiole 
• 96753-96-7 1-(2,3-dimethoxy-4,5-methylenedioxyphenyl)but-1-en-3-one 
• 96753-97-8 1,4-di(2,3-dimethoxy-4,5-methylenedioxyphenyl)pent-1,4-dien-3-one 
• 38971-74-3 Dillapional 
• 1133322-54-9 3-(4-methoxyphenyl)-5-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-4-methyl-4,5-dihydroisoxazole 
• 1133322-55-0 3-(4-methoxyphenyl)-4-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-5-methyl-4,5-dihydroisoxazole 
• 936083-47-5 4-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-5-methyl-3-(2,4,6-trimethylphenyl)-4,5-dihydroisoxazole 
• 1133322-60-7 5-(2,3-dimethoxy-4,5-methylenedioxyphenyl)-4-methyl-3-(2,4,6-trimethylphenyl)-4,5-dihydroisoxazole 
• 96573-28-3 2,3-dimethoxysesamyl γ,γ-dimethylallylether 
• 96573-18-1 2,3-dimethoxysesamyl n-hexylether 

Relevant academic research and scientific papers

A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds

A polymer-supported iridium catalyst has been prepared and used in the isomerisation of the double bonds in aryl allylic derivatives with excellent trans selectivity and without the need for conventional work-up procedures.

A concise synthesis of carpanone using solid-supported reagents and scavengers

The synthesis of the natural product carpanone by utilization of polymer supported reagents, eliminating the need for conventional purification techniques was reported. The synthesis and crystal structure of a polymer-supported iridium catalyst for isomerization was also reported. The observations showed that isomerization of electron-rich aromatic compounds by the catalyst resulted in products with predominantly trans alkene geometry. However, the electron-poor derivatives were found to be less prone to rearrangement.

Photon-Induced Reactions: Part V - Photochemical and Chemical Oxidation Products of Dillapiole and Isodillapiole

Several photometabolites of dillapiole (1), obtained by irradiating it in methanol have been identified as isodillapiole (2), dihydrodillapiole (3), 1-cyclopropyl-2,3-dimethoxy-4,5-methylenedioxybenzene (4), dillaldehyde (7) and two new methanol adducts (5) and (6).Isodillapiole (2) under the same conditions furnishes 5, 6 and 7.Dye-sensitized photooxidation of 1 gives, besides the aldehydes 7 and 8, dihydroxydillapiole (11).For comparison, KMnO4 oxidation of 1 has also been investigated in detail.