96850-48-5

Upstream product

• 96850-53-2 (2S^*,3R^*,1'S^*)-3-benzyloxy-2-isopropyl-3-(spiro<2.4>hepta-4,6-dien-1-yl)propanal 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 556-24-1 methyl 3-methylbutanoate 
• 51473-85-9 R(S)-spiro[2.4]hepta-4,6-dien-1-ylmethanol 
• 93093-38-0 1-carboxaldehydespiro<2.4>hepta-4,6-diene 
• 96850-52-1 (R)-2-((S)-Hydroxy-(R)-spiro[2.4]hepta-4,6-dien-1-yl-methyl)-3-methyl-butyric acid methyl ester 
• 96850-47-4 (2S^*,3R^*,1'S^*)-3-benzyloxy-2-propyl-3-(spiro<2.4>hepta-4,6-dien-1-yl)propanol 
• 112280-70-3 (S)-2-((R)-Benzyloxy-(S)-spiro[2.4]hepta-4,6-dien-1-yl-methyl)-3-methyl-butyric acid methyl ester 
• 96850-53-2 (S)-2-((S)-Benzyloxy-(R)-spiro[2.4]hepta-4,6-dien-1-yl-methyl)-3-methyl-butyraldehyde 
• 96850-52-1 methyl (2R^*,3R^*,1'S^*)-3-hydroxy-2-isopropyl-3-(spiro<2.4>hepta-4,6-dien-1-yl)propanoate 
• 96850-47-4 (R)-2-((S)-Benzyloxy-(R)-spiro[2.4]hepta-4,6-dien-1-yl-methyl)-3-methyl-butan-1-ol 
• 112280-70-3 (R)-2-((R)-Benzyloxy-(S)-spiro[2.4]hepta-4,6-dien-1-yl-methyl)-3-methyl-butyric acid methyl ester 

Downstream Products

• 96850-49-6 5-benzyloxy-6-isopropyl-8-carbomethoxytetracyclo<5.4.0^1.7.0^2.4.0^2.9>undec-10-ene 
• 64845-75-6 (+/-)-sinularene 
• 96850-49-6 C₂₃H₂₈O₃ 
• 64845-75-6 (+/-)-5-epi-sinularene 

Relevant academic research and scientific papers

Stereoselective total syntheses of (+/-)-sinularene and (+/-)-5-epi-sinularene: a general intramolecular Diels-Alder approach to tricyclic sesquiterpenes

Stereoselective total synthesis of (+/-)-sinularene and (+/-)-5-epi-sinularene are described.The sequence employs a "blocked" cyclopentadiene in which the cyclopropane unit also serves as a latent methyl group.Thus intramolecular cycloaddition of th