96850-92-9Relevant academic research and scientific papers
DEBENZYLATION OF N-BENZYL-β-LACTAMS BY USE OF ANODIC OXIDATION
Mori, Miwako,Ban, Yoshio
, p. 317 - 323 (2007/10/02)
Anodic oxidation of N-benzyl-3-methylene-β-lactam 1a followed by hydrolysis with TsOH in 2-butanone gave 3-methylene-β-lactam 4a.To examine the effect of the substituents on the aromatic ring of N-benzyl group for the anodic oxidation, N-p-carbomethoxy, N
ANODIC OXIDATION OF N-ALKYL-β-LACTAMS
Okita, Makoto,Mori, Miwako,Wakamatsu, Takeshi,Ban, Yoshio
, p. 247 - 250 (2007/10/02)
β-Lactams were electrolyzed in an undivided cell with platinum plate as anode in methanol under constant current.The oxidation of β-lactams 5 and α-methylene-β-lactams 10 proceeded both at the exo- and endo-cyclic carbons α to nitrogen, Though five, six and seven membered lactams were regioselectively electrolyzed under the same conditions.
