96864-08-3

Basic information

• Product Name: <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> hexanoate
• Synonyms: <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> hexanoate
• CAS NO: 96864-08-3
• Molecular Weight: 495.767
• Mol File: 96864-08-3.mol

Chemical Properties

• CAS DataBase Reference: <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> hexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> hexanoate(96864-08-3)
• EPA Substance Registry System: <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> hexanoate(96864-08-3)

Safety Data

• Hazardous Substances Data: 96864-08-3(Hazardous Substances Data)

Upstream product

• 96303-88-7 (-)-10-dicyclohexylsulfamoyl-D-isoborneol 
• 142-61-0 Hexanoyl chloride 
• 104897-97-4 (S)-Chloro-phenyl-acetic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 104897-98-5 (S)-2-Bromo-4-methyl-pentanoic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 104897-94-1 (S)-2-Chloro-propionic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 104897-90-7 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((Z)-2-phenyl-1-trimethylsilanyloxy-vinyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 104897-86-1 Phenyl-acetic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 104897-91-8 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((E)-4-methyl-1-trimethylsilanyloxy-pent-1-enyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 104897-88-3 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((E)-1-trimethylsilanyloxy-propenyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 104926-26-3 <(2S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> 4-methylvalerate 
• 96864-31-2 <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl>propionate 
• 638-29-9 n-valeryl chloride 

Downstream Products

• 104897-89-4 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((E)-1-trimethylsilanyloxy-hex-1-enyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 104897-89-4 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((Z)-1-trimethylsilanyloxy-hex-1-enyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 
• 104897-95-2 (S)-2-Bromo-hexanoic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 110449-51-9 <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> (2R)-2-aminohexanoate 
• 110449-42-8 <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> <(2S)-2-(N,N'-di-tert-butoxycarbonyl)>hydrazinohexanoate 
• 96303-88-7 (-)-10-dicyclohexylsulfamoyl-D-isoborneol 
• 22628-26-8 L-norleucine ethyl ester 
• 119751-26-7 <(1S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> <(2R)-2-(N,N'-di-tert-butoxycarbonyl)>hydrazinohexanoate 
• 327-56-0 D-norleucine 
• 327-57-1 L-Norleucine 
• 106749-05-7 (R)-2-Azido-hexanoic acid (1S,2R,4R)-1-[(dicyclohexylsulfamoyl)-methyl]-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 1436-34-6 (R)-1,2-epoxyhexane 
• 104926-26-3 <(2S,2R)-10-(N,N-dicyclohexylaminosulfonyl)born-2-yl> 4-methylvalerate 
• 104897-91-8 N,N-Dicyclohexyl-C-[(1S,2R,4R)-7,7-dimethyl-2-((E)-4-methyl-1-trimethylsilanyloxy-pent-1-enyloxy)-bicyclo[2.2.1]hept-1-yl]-methanesulfonamide 

Relevant articles and documents

ENANTIOSELECTIVE SYNTHESES OF α-AMINO ACIDS FROM 10-SULFONAMIDO-ISOBORNYL ESTERS AND DI-t-BUTYL AZODICARBOXYLATE

Successive treatment of chiral esters 7 with LDA/Me3SiCl and di-t-butyl azodicarboxylate/TiCl4 and Ti(OiPr)4 gave N,N-di-t-butoxycarbonylhydrazinoesters 11 which on deacylation, hydrogenolysis, transesterification and acidic hydrolysis furnished (2S)-α-amino acid hydrochlorides 13 in good overall yields, high enantiomeric purity and with efficient recovery of the alcohol auxiliary 4.Experimental evidence for the configuration and conformation of the intermediate O-silyl ketene acetals 1 is provided.

ASYMMETRIC HALOGENATION OF CAMPHOR-10-SULFONIC ACID DERIVED ESTERS: AN EFFICIENT NEW ROUTE TO ENANTIOMERICALLY PURE HALOHYDRINS AND EPOXIDES.

Successive treatment of chiral esters 1 with LDA/Me3SiCl and NBS or NCS gave crystalline α-haloesters 3 which furnished halohydrins 4 and terminal epoxides 5 in high e.e..