96865-76-8Relevant academic research and scientific papers
Electrophilic Carbenoids. FRormation and Trapping of an Anti-Bredt Vinyllithium
Warner, Philip M.,Chang, Suae-Chen,Koszewski, Nicholas J.
, p. 2605 - 2606 (1985)
The reaction of 9,9-dichloropropell-3-ene (1) with excess n-BuLi produces a lithium carbenoid which shows exceptional electrophilic reactivity, which includes reaction via cationic ring-opening to afford an anti-Bredt vinyllithium intermediate, 10.
