Journal of Organic Chemistry p. 2605 - 2606 (1985)
Update date:2022-08-03
Topics:
Warner, Philip M.
Chang, Suae-Chen
Koszewski, Nicholas J.
The reaction of 9,9-dichloro<4.3.1>propell-3-ene (1) with excess n-BuLi produces a lithium carbenoid which shows exceptional electrophilic reactivity, which includes reaction via cationic ring-opening to afford an anti-Bredt vinyllithium intermediate, 10.
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