96866-63-6Relevant articles and documents
N-Methylpiperidine N-Oxide as a Source of Nonstabilized Ylide: A New and Efficient Route to Octahydroindolizine Derivatives
Chastanet, J.,Roussi, G.
, p. 2910 - 2914 (2007/10/02)
N-Methylpiperidine N-oxide in the presence of LDA reacts with various nonactivated olefins to give high yields of the corresponding octahydroindolizines.The structure of the nonstabilized ylide intermediate allows the study of the regiochemistry and stereochemistry of this new cycloaddition reaction.