96871-58-8

Upstream product

• 7699-79-8 benzhydrylidene-benzyl-amine 
• 908093-98-1 diazodiphenylmethane 
• 201024-81-9 C,N-diphenylnitrone 
• 17599-59-6 diphenylmethyleneaminotrimethylsilane 
• 74225-38-0 C₂₉H₃₀N₂OSi 

Downstream Products

• 119-61-9 benzophenone 
• 5700-60-7 1,2-Diphenylethylenediamine 
• 342587-61-5 dl-N,N'-bis(diphenylmethyl)-1,2-diphenyl-1,2-ethanediamine 

Relevant academic research and scientific papers

Reactions of Trimethylsilyl Cyanide and N-(Trimethylsilyl)diphenylmethyleneamine with Nitrones and Thermal Decompositions of Their Adducts

Trimethylsilyl cyanide (1) and N-(trimethylsilyl)diphenylmethyleneamine (2) reacted with α-aryl-N-phenylnitrones to afford the corresponding 1:1 adducts 4 and 5 respectively.Thermal decomposition of 4 in refluxing xylene gave azoxybenzene, stereoisomers of 2,3-diarylsuccinonitriles, α-aminonitriles and/or benzanilides, whose yields depended on the nature of substituents on phenyl group of 4.On heating in benzene 5 afforded a mixture of azoxybenzene and meso-N,N'-bis(diphenylmethylene)-1,2-diarylethylenediamines.On the other hand, reactions of 1 and 2 with N-(diphenylmethylene)aniline N-oxide or N-(9-fluorenylidene)aniline N-oxide did not give the corresponding 1:1 adducts, but instead compounds arising from thermal decomposition of initial 1:1 adducts were directly obtained.The reaction of 1 with N-(p-diethylaminophenyl)-α-phenylnitrone leading to the corresponding α-imino nitrile is also described.

Radical Dimerisation During Reaction of Diphenyldiazomethane with Benzophenone-N-benzylimine

Thermal and photochemical reactions of diphenyldiazomethane (I) with benzophenone-N-benzylimine (II) gives dl-N,N'-bis(diphenylmethylene)-1,2-diphenyl-1,2-ethanediamine (V), besides benzophenoneazine (III) and 1:1 molecular complex (IV) of III with 1,1,2,