17599-59-6

Basic information

• Product Name: Silanamine, N-(diphenylmethylene)-1,1,1-trimethyl-
• CAS NO: 17599-59-6
• Molecular Formula: C16H19NSi
• Molecular Weight: 253.419
• Mol File: 17599-59-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Silanamine, N-(diphenylmethylene)-1,1,1-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N-(diphenylmethylene)-1,1,1-trimethyl-(17599-59-6)
• EPA Substance Registry System: Silanamine, N-(diphenylmethylene)-1,1,1-trimethyl-(17599-59-6)

Safety Data

• Hazardous Substances Data: 17599-59-6(Hazardous Substances Data)

Upstream product

• 1574-41-0 Z-piperylene 
• 80431-36-3 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan 
• 624-64-6 trans-2-Butene 
• 542-92-7 cyclopenta-1,3-diene 
• 106-99-0 buta-1,3-diene 
• 80431-44-3 2,3,4,4a-Tetrahydro-3,3-dimethyl-1-phenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 67-64-1 acetone 
• 119-61-9 benzophenone 
• 70582-00-2 1,1,1,3,3-pentamethyldisilazane 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 101-81-5 Diphenylmethane 
• 124-38-9 carbon dioxide 
• 4039-32-1 lithium hexamethyldisilazane 

Downstream Products

• 19959-23-0 Benzhydrylidene-(chloro-diphenyl-methyl)-amine 
• 495-48-7 azoxybenzene 
• 85019-57-4 C₂₆H₂₄F₃N₃O₂Si 
• 113613-42-6 Benzhydrylidene-[chloro-bis-(4-chloro-phenyl)-methyl]-amine 
• 20912-56-5 1,1-diphenylethylamine 
• 130024-40-7 N-diphenylmethylene-N'-(4-methylphenyl)benzamide 
• 78375-55-0 1,1-bis(trimethylsilyl)-2,2-diphenylethylene 
• 80431-44-3 2,3,4,4a-Tetrahydro-3,3-dimethyl-1-phenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin 
• 80431-45-4 N-silyl>benzophenonimin 
• 80431-36-3 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan 
• 67206-31-9 Lithium-diphenyl-phosphat 
• 54008-64-9 1,1,3,3-tetramethyl-2,2,4,4-tetrakis(trimethylsilyl)-1,3-disilacyclobutane 
• 106710-87-6 4,4-Diphenyl-2,2-bis(trideuteriomethyl)-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan 
• 117984-32-4 2,3,4,4a-Tetrahydro-1,3,3-triphenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin 

Relevant articles and documents

The chemical behavior of the silaoxine C22H34OSi3 and silaazetidine C25H43NSi4 towards CO2

When 4,4a-dihydro-3,3-dimethyl-1-phenyl-4,4-bis(trimethylsilyl)-3H-2-oxa-3-sila-naphthaline (silaoxine C22H34OSi3 (3); orthorhombic, space group Pna21, Z=4) was thermolized in a CO2 atmosphere, the co

Reactions of lithium hydridosilylamides with carbonyl compounds and mixtures of carbonyl compounds and chlorotrimethylsilane

The lithium hydridosilylamides Me2(H)SiN(Li)R (1: R = CMe3, 2: R = SiMe3) were allowed to react either with the non-enolizable carbonyl compounds CH2=C(Me)CHO, PhCHO and Ph2CO followed by trapping with chlorotrimethylsilane (A), or with mixtures of these carbonyl compounds and chlorotrimethylsilane (B). In the second case the course of the reactions is determined by the carbonyl compound. The composition of the reaction mixtures is nearly the same according to A and B. Main products in the reactions with the aldehydes are the corresponding imines R1CH=NR R1 = CH2=C(Me), Ph) 3, 4, 8, 9 formed by addition of the hydridosilylamides to the C=O group of the aldehydes and subsequent LiOSiMe2H elimination. Partial hydrosilylation of the aldehydes by the hydridosilanolate followed by the trimethylsilylation yields the alkoxydisiloxanes R1CH2OSiMe2OSiMe3 6, 11. In some cases 2 partially reacts under hydrosilylation to give the alkoxydisilazanes R1CH2OSiMe2NHSiMe3 7, 12. The hydrosilylation is the preferred reaction of 1 and 2 with benzophenone. The compounds Ph2CHOSiMe2NHR 13, 14 are obtained. This difference in the reaction behaviour of 1 and 2 towards the aldehydes and benzophenone is mainly due to steric reasons. Depending on the conditions the imines Ph2C=NR 20, 21 may be formed. Ph2CHOSiMe2OSiMe3 (22) is a secondary product of imine formation. In all reactions of 1 and 2 with the carbonyl compounds the corresponding alkoxysilanes R1CH2OSiMe3 (5: R1 = CH2=C(Me), 6: R1 = Ph) and Ph2CHOSiMe3 (15) are generated. Compounds resulting from a reaction of 1 and 2 with chlorotrimethylsilane are produced to minor extent, but only if the molar ratio of amide to carbonyl compounds is not greater than one. The formation of a silanimine intermediate in reaction according to B is not observed.