96888-16-3Relevant academic research and scientific papers
RING OXYGENATED INDOLE GLUCOSINOLATES OF BRASSICA SPECIES
Hanley, A. B.,Belton, P. S.,Fenwick, G. R.,Janes N. F.
, p. 598 - 600 (1985)
Key Word Index - Brassica napus subsp. napobrassica; Brassica napus subsp. oleifera; Cruciferae; swede; rape; structural confirmation; indole glucosinolates. - Detailed chemical, degradative and spectroscopic analysis of two ring oxygenated indole glucosinolates isolated from Brassica species has confirmed these to be substituted in 4- rather than the 5-position, although the latter had been suggested on biosynthetic grounds.
A SYNTHESIS METHOD OF INDOLE-3-METHANAMINE AND/OR GRAMINE FROM INDOLE-3-CARBOXALDEHYDE, AND ITS APPLICATION FOR THE SYNTHESES OF BRASSININ, ITS 4-SUBSTITUTED ANALOGS, AND 1,3,4,5-TETRAHYDROPYRROLOQUINOLINE
Yamada, Fumio,Kobayashi, Kensuke,Shimizu, Aya,Aoki, Naokatsu,Somei, Masanori
, p. 2783 - 2804 (2007/10/02)
Simple conversion method of indole-3-carboxaldehyde into gramine and/or indole-3-methanamine was developed.The present method realized short step syntheses of brassinin, 4-iodo-, methoxy-, 4-methoxy, and 4-nitrobrassinin, 4-methoxyindole-3-acetonitrile, and 1,3,4,5-tetrahydropyrroloquinoline.
