96890-24-3Relevant academic research and scientific papers
C3-homologation. Synthesis of C19-skipped polyenic pheromones
Viala,Munier,Santelli
, p. 3347 - 3352 (2007/10/02)
Total synthesis of three sex pheromone components including an all-cis diene or triene unit are described. Starting from decanal, cis-Wittig reactions, by using C3 homologating agent 4 and convenient phosphonium salts, allowed us to built up all-cis skipp
Synthesis of (Z,E)- and (Z,Z)-α-Farnesenes and -Homofarnesenes
Morgan, E. David,Thompson, Lorna D.
, p. 399 - 404 (2007/10/02)
The ant substance (Z,E)-α-farnesene and its isomer (Z,Z)-α-farnesene have been synthesized in an overall yield of 34percent in six stages from methyl cyclopropyl ketone and 6-methylhept-5-en-2-one via a Wittig condensation.A mixture of the corresponding (Z,E)-α-homofarnesene of ants and its (Z,Z) isomer were prepared in much poorer yield by the same method and incompletely characterized.The isomeric identification of both insect materials were confirmed.
