96914-63-5Relevant academic research and scientific papers
Direct Cyclopropanation of α-Cyano β-Aryl Alkanes by Light-Mediated Single Electron Transfer Between Donor–Acceptor Pairs
Li, Jing,Lear, Martin J.,Hayashi, Yujiro
, p. 5901 - 5905 (2021/03/09)
Cyclopropanes are traditionally prepared by the formal [2+1] addition of carbene or radical based C1 units to alkenes. In contrast, the one-pot intermolecular cyclopropanation of alkanes by redox active C1 units has remained unrealised. Herein, we achieve
Cyclopropanation of Electrophilic Alkenes With Nitroalkanes in the Presence of Alumina-Supported Potassium Fluoride
Melot, Jean-Marie,Texier-Boullet, Francoise,Foucaud, Andre
, p. 364 - 366 (2007/10/02)
Alumina-supported potassium fluoride is an effective reagent for Michael addition of nitroalkanes on the electrophilic alkenes, followed by cycloalkylation reaction to give cyclopropanes.
Nitro Compounds as Nucleophilic Alkylidene Transfer Reagents
Ono, Noboru,Yanai, Tetsuya,Hamamoto, Isami,Kamimura, Akio,Kaji, Aritsune
, p. 2806 - 2807 (2007/10/02)
Nitro compounds can be used as useful and general nucleophilic alkylidene transfer reagents for the preparation of various cyclopropanes.
