97004-64-3

Basic information

• Product Name: 1,3-Dihydro-1-methyl-3-(4-methylphenyl)-3-phenyl-2H-indol-2-on
• Synonyms: 1,3-Dihydro-1-methyl-3-(4-methylphenyl)-3-phenyl-2H-indol-2-on
• CAS NO: 97004-64-3
• Molecular Weight: 313.399
• Mol File: 97004-64-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3-Dihydro-1-methyl-3-(4-methylphenyl)-3-phenyl-2H-indol-2-on(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dihydro-1-methyl-3-(4-methylphenyl)-3-phenyl-2H-indol-2-on(97004-64-3)
• EPA Substance Registry System: 1,3-Dihydro-1-methyl-3-(4-methylphenyl)-3-phenyl-2H-indol-2-on(97004-64-3)

Safety Data

• Hazardous Substances Data: 97004-64-3(Hazardous Substances Data)

Upstream product

• 86839-46-5 r-2-Ethoxy-t-3-hydroxy-1-methyl-3-phenyl-2-p-tolylindolin 
• 108-86-1 bromobenzene 
• 3335-97-5 1-methyl-3-phenylindolin-2-one 
• 106-38-7 para-bromotoluene 
• 61-70-1 N-methyl-2-indolinone 

Relevant articles and documents

Enantioselective Arylation of Oxindoles Using Modified BI-DIME Ligands

The Pd-catalyzed 3-arylation of 2-oxindoles with aryl bromides, chlorides and triflates is found to proceed using i -Pr-BI-DIME and Me 2 -BI-DIME ligands. The mono-arylation of 3-unsubstituted oxindoles is accomplished using a Pd 2 (dba) 3 / i -Pr-BI-DIME catalyst system, and gives good yields of 3-aryloxindoles from aryl bromides and chlorides. The arylation of 3-substituted oxindoles is also possible using this catalyst/ligand system. The asymmetric arylation of 3-substituted oxindoles is accomplished using Me 2 -BI-DIME to furnish oxindoles bearing a quaternary C-3 stereocenter in enantiomeric ratios of up to 93:7.