97067-26-0Relevant academic research and scientific papers
QUELQUES PROPRIETES CHIMIQUES DU TRIS(TERTIOBUTYL)-2,4,6 PHENYLDITHIOPHOSPHORANE
Navech, J.,Revel, M.,Kraemer, R.,Mathieu,S.
, p. 83 - 90 (2007/10/02)
The chemical properties of the dithiometaphosphonate analogue, tris(2,4,6-t-butyl)phenyldithiophosphorane (1), are reported in detail.
ETUDE DE LA REACTIVITE DU TRIS(TERTIOBUTYL)PHENYLDITHIOPHOSPHORANE
Navech, J.,Revel, M.,Kraemer, R.
, p. 207 - 210 (2007/10/02)
Heating of tris(tertiobutyl)phenyldithiophosphorane gives rise to an isomer with a tetracoordinated phosphorus atom.The action of triphenylphosphine loads to a tricyclophosphathiane which can be transformed in diphosphene by an excess of triphenylphosphine.Reactions with various nucleophilic derivatives (pyridine, triethylamine, diethylamine, butylamine, water, tetraphenylarsonium chloride) are described.
