97202-06-7Relevant academic research and scientific papers
Versatile behavior of the schiff base ligand 2,5-Me2C 6H3C(H)=N(2,4,6-Me3C6H2) toward cyclometalation reactions: C(sp2,phenyl)-H vs C(sp 3,methyl)-H activation
Vazquez-Garcia, Digna,Fernandez, Alberto,Lopez-Torres, Margarita,Rodriguez, Antonio,Gomez-Blanco, Nina,Viader, Carlos,Vila, Jose M.,Fernandez, Jesus J.
, p. 3303 - 3307 (2010/09/17)
Treatment of the Schiff base ligand a with palladium(II) acetate in toluene gave 1a, with metalation of an aromatic phenyl carbon atom. Reaction at room temperature gave the trinuclear complex 4a. Treatment of a with palladium(II) acetate in refluxing acetic acid gave 1a′. The reaction of complexes 1a and 1a′ with sodium chloride or lithium bromide gave the halogen-bridged complexes 2a, 3a, 2a′, and 3a′.
