97204-76-7Relevant academic research and scientific papers
Synthesis of 1 C -Aryl/Alkyl 2 C -Branched Sugar-Fused Isochroman Derivatives by Sequential Prins and Friedel-Crafts Cyclizations on a Perlin Aldehyde Derived Substrate
Rajasekaran, Parasuraman,Mallikharjunarao, Yakkala,Vankar, Yashwant D.
, p. 1346 - 1352 (2017)
The synthesis of C -aryl/alkyl 2 C -branched sugar-fused isochromans by using a carbohydrate-derived starting material is described. Our approach makes use of sequential Prins and Friedel-Crafts cyclizations in which a Perlin aldehyde derived homoallylic
Diastereoselective synthesis of the C29-C41 fragment of karlotoxin 2
Reddy, D. Srinivas,Gaddam, Janardhan,Devunuri, Nagaraju,Mohapatra, Debendra K.
, p. 4299 - 4301 (2015/06/22)
A highly diastereoselective synthesis of the C29-C41 fragment of karlotoxin 2 (KmTx2) is described by employing regio-selective epoxide opening, our own developed domino isomerization followed by C-O and C-C bond formation reaction and chelation-controlled Grignard reaction as key steps. The synthesis involves installation of seven stereocenters present in the C29-C41 fragment of karlotoxin 2.
InCl3-CH3CN-H2O: An efficient catalyst-solvent combination for the synthesis of Perlin aldehydes and related compounds. Application in the synthesis of unnatural l-azasugars
Nagaraj, Paramathevar,Ganesan, Muthupandian,Ramesh, Namakkal G.
experimental part, p. 769 - 776 (2011/03/19)
InCl3-CH3CN-H2O has been found to be an efficient catalyst-solvent combination for the synthesis of Perlin aldehydes and related compounds. While acetylated glycals afforded the Perlin aldehydes directly with InCl3/s
A versatile route for the stereoselective synthesis of oxybiotin
Reddy, Lingala Vijaya Raghava,Swamy, Golla Narayana,Shaw, Arun K.
, p. 1372 - 1375 (2008/12/20)
An efficient 10-step synthesis of oxybiotin, an oxygen analogue of biotin, is disclosed starting from 3,4,6-tri-O-benzyl-d-glucal.
An efficient synthesis of 2,3-dideoxy-α,β-unsaturated carbohydrate enals by mixed Lewis acid (HfCl4 and ZnI2) catalyzed hydration of glycals
Saquib, Mohammad,Sagar, Ram,Shaw, Arun K.
, p. 1052 - 1056 (2007/10/03)
A new, efficient method has been developed for converting acyl-, arylalkyl- and alkyl-protected glycals into corresponding 2,3-dideoxy-α,β-unsaturated carbohydrate enals utilizing the in situ generated push-pull effect resulting from the synergistic combi
(E)-(4R)-dibenzyloxy hex-2-enal 1-(ethylene acetal): A new chiral compound useful for eicosanoid synthesis
Lellouche,Quinton
, p. 1979 - 1988 (2007/10/02)
The preparation of the new six carbon multifunctionalized chiral synthon 4, useful for eicosanoid synthesis, was achieved employing the Perlin hydrolysis reaction of 3,4,6-tri-O-benzyl-D-Glucal 6 in the key step.
