97205-25-9

Upstream product

• 97205-24-8 8-methoxycarbonyloct-1-yl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 56343-03-4 8-methoxycarbonyloct-1-yl 2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 

Downstream Products

• 97205-11-3 8-methoxycarbonyloct-1-yl-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1-3)-O-(4-O-acetyl-2,6-di-O-benzoyl-β-D-galactopyranosyl)-(1-4)-2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-01-3 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-09-1 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(tetra-O-acetyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173096-98-5 8-methoxycarbonyloct-1-yl 2-acetamido-3,6-di-O-benzyl-2-deoxy-4-O-(β-D-galactopyranosyl)-β-D-glucopyranoside 
• 173097-00-2 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(tetra-O-acetyl-β-D-galactopyranosyl)-6-O-benzoyl-2-deoxy-β-D-glucopyranoside 
• 173097-07-9 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-05-7 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-06-8 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(4-O-acetyl-2,6-di-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-04-6 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(2,3-di-O-benzyl-4,6-O-isopropylidene-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-03-5 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(2,6-di-O-benzyl-3,4-O-isopropylidene-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-02-4 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(3,4,6-tri-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 173097-08-0 8-methoxycarbonyloct-1-yl 2-acetamido-4-O-(6-O-benzoyl-2,3-di-O-benzyl-β-D-galactopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis and 1H NMR characterization of the six isomeric mono-O-sulfates of 8-methoxycarbonyloct-1-yl O-β-D-galactopyranosyl-(14)-2-acetamido-2-deoxy-β-D-glucopyranoside

All six isomeric mono-O-sulfates of β-D-Gal p-(1->4)-β-D-Glc pNAc-O-(CH2)8COOMe(LacNAc-MCO) have been chemically synthesized and characterized by high resolution 1H NMR spectroscopy.Sulfation causes characteristic substitution-site-specific downfield shif

A SYNTHESIS OF 8-METHOXYCARBONYLOCT-1-YL O-α-D-GALACTOPYRANOSYL-(1->3)-O-β-D-GALACTOPYRANOSYL-(1->4)-2-ACETAMIDO-2-DEOXY-β-D-GLUCOPYRANOSIDE

Halide assised glycosylation, using a non-participating 2-substituent (benzyl) in the glycosyl halide, was used to obtain the α-D-galactosyl linkage and silver triflate promotion with a participating 2-substituent (benzoyl) was used to obtain the β-D-gala