97218-68-3Relevant academic research and scientific papers
Highly Diastereoselective Reduction of Chiral β-Ketosulphoxides under Chelation Control: Application to the Synthesis of (R)-(+)-n-Hexadecano-1,5-lactone
Kosugi, Hiroshi,Konta, Hiroshi,Uda, Hisashi
, p. 211 - 213 (2007/10/02)
The presence of zinc chloride in the reduction of chiral β-ketosulphoxides with di-isobutylaluminium hydride effects high 1,3-asymmetric induction to give β-hydroxysulphoxides; this method can be successfully applied to the synthesis of optically pure 1,4
