97231-52-2Relevant academic research and scientific papers
Phenylthio (and phenylseleno)fluorination of alkenes and alkynes using N-phenylthio (and phenylseleno)phthalimide combined with pyridine*9HF or Et3N*3HF complexes
Saluzzo, Christine,Spina, Anna-Maria La,Picq, Dominique,Alvernhe, Gerard,Anker, Daniel,et al.
, p. 831 - 843 (2007/10/02)
N-Phenylthiophthalimide and N-phenylselenophthalimide combined with pyridine*9HF or Et3N*3HF complexes allow the formal addition of elements of PHSF or PhSeF across the carbon-carbon double or triple bond by a one-pot reaction.Pyridine*9HF, a strongly aci
SYNTHESIS OF β-FLUOROALKYL PHENYL (OR METHYL) THIOETHERS BY SULFUR-ASSISTED HALOGEN EXCHANGE WITH TRIETHYLAMINE TRIS-HYDROFLUORIDE
Saluzzo, C.,Alvernhe, G.,Anker, D.,Haufe, G.
, p. 467 - 479 (2007/10/02)
The exchange of chlorine in β-chloroalkyl phenyl (or methyl) thioethers by fluorine, with anchimeric assistance of sulfur, is very easily realized with the almost neutral fluorinating reagent, Et3N*3HF.The 'one-pot' reactions of alkenes with sulfenyl chlo
The Preparation of β-Fluoro Thioethers
Purrington, Suzanne T.,Correa, Itzela D.
, p. 1080 - 1083 (2007/10/02)
Addition of benzenesulfenyl chloride to electron-rich olefins in the presence of silver produces β-fluoro thioethers.The trans adducts could also be prepared from β-chloro thioethers and silver fluoride.
