97249-36-0Relevant academic research and scientific papers
Stereocontrol of stereogenic centres para on a benzene ring using the SE2″ reaction of a pentadienylsilane
Fleming, Ian,Leslie, Colin P.
, p. 1197 - 1203 (1996)
The pentadienylsilane 9 and the dimethyl acetal 2 of isobutyraldehyde react with high (80:20) anti stereospecificity to give largely the diene 10a, which was converted into the Para-disubstituted benzene 11a, having 1,6-related stereogenic centres.
A SYNTHESIS OF THE PRELOG-DJERASSI LACTONE USING OPEN-CHAIN STEREOCONTROL BASED ON ALLYLSILANE CHEMISTRY
Chow, Hak-Fun,Fleming, Ian
, p. 397 - 400 (2007/10/02)
A stereocontrolled synthesis of the Prelog-Djerassi lactone (28) is described; all the stereocontrol sterms from the high diastereoselectivity of electrophilic attack on a double bond adjacent to a chiral centre carrying a silyl group.
