97271-13-1Relevant articles and documents
DIASTEREOTOPIC GROUP SELECTIVITY AT A PROSTEREOGENIC CARBON CENTER: SYNTHESIS OF (+/-)-SYN-4,8-DIMETHYLDECANAL
Schreiber, Stuart L.,Hulin, Bernard
, p. 4561 - 4564 (2007/10/02)
A group selective dealkylation reaction of a bridged ketal with trimethylsilyl iodide serves to control stereochemistry at carbon centers that are separated by five atoms.In combination with the iron/copper promoted fragmentation reaction of a hydroperoxi
New Synthesis of (4R,8R)-4,8-Dimethyldecanal, the Aggregation Pheromone of Tribolium castaneum, and its (4R,8S)-Isomer
Mori, Kenji,Kato, Minoru,Kuwahara, Shigefumi
, p. 861 - 865 (2007/10/02)
Die Synthese der Titelverbindungen (4R,8R)-1 und (4R,8S)-1 aus (R)-Citronellsaeure wird beschrieben.Die Anwendung der Kolbe-Elektrolyse ist der Schluesselschritt der Synthese.