97290-59-0Relevant academic research and scientific papers
Stereocontrolled Synthesis of N-Vinyl-, N-(1'-Propenyl)-, and N-Unsubstituted-β-lactams from 2-Aza-1,3-butadienes via the Staudinger Reaction
Georg, Gunda I.,He, Ping,Kant, Joydeep,Wu, Zhi-jun
, p. 5771 - 5778 (2007/10/02)
2-Aza-1,3-butadienes 2 and 5 were synthesized in good yields and on a large scale.Reaction of 2 and 5 with acid chlorides in the presence of triethylamine (Staudinger reaction) resulted in the high-yielding formation of N-vinyl- and N-(1'-propenyl)-β-lact
A Protodesilylation Route for 2-Aza-1,3-diene Synthesis
Chen, Shyh-Fong,Ho, Eugene,Mariano, Patrick S.
, p. 7013 - 7026 (2007/10/02)
A new methodology for 2-aza-1,3-diene synthesis involving protodesilylation reactions of N-1-triethylsilylallyl-imines and their propargyl analogs is described.Synthetic sequences for the preparation of these allyl and propargyl imines starting with propa
MECHANISTIC AND SYNTHETIC ASPECTS OF 2-AZA-1,3-DIENE PREPARATION THROUGH N-(1-TRIETHYLSILYLALLYL)IMINE PROTODESILYLATION
Chen, Shyh-Fong,Mariano, Patrick S.
, p. 47 - 50 (2007/10/02)
Features of a novel method for preparation of 2-aza-1,3-dienes involving CsF induced protodesilylation of N-(1-triethylsilylallyl)imines is described.
