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A New -Type Annelation Useful for the Formation of Piperidine Skeletons
Shono, Tatsuya,Matsumura, Yoshihiro,Uchida, Kenshi,Kobayashi, Hidekazu
, p. 3243 - 3245 (1985)
A -type annelation between α,α'-dimethoxylated amides 4 and allyltrimethylsilane (5) gave piperidine derivatives 6.It was applied to the synthesis of piperidine, indolizidine, quinolizidine, 1-azabicycloundecane, 1-aza-8-oxabicyclononane, 8-azabicyclooctane, and 9-azabicyclononane derivatives.
