A New -Type Annelation Useful for the Formation of Piperidine Skeletons

DOI: 10.1021/jo00217a056

Source and publish data:

Journal of Organic Chemistry p. 3243 - 3245 (1985)

Update date:2022-07-30

Topics:

Authors:

Shono, Tatsuya

Matsumura, Yoshihiro

Uchida, Kenshi

Kobayashi, Hidekazu

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Article abstract of DOI:10.1021/jo00217a056

A <3 + 3>-type annelation between α,α'-dimethoxylated amides 4 and allyltrimethylsilane (5) gave piperidine derivatives 6.It was applied to the synthesis of piperidine, indolizidine, quinolizidine, 1-azabicyclo<5.4.0>undecane, 1-aza-8-oxabicyclo<4.3.0>nonane, 8-azabicyclo<3.2.1>octane, and 9-azabicyclo<3.3.1>nonane derivatives.

Full text of DOI:10.1021/jo00217a056

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