97336-65-7Relevant academic research and scientific papers
Reactions of Lithium Bicyclobutan-2-olates Formed by Carbenoid Type Decomposition of Lithiothioacetal Enolates. A Novel Concept for One-Pot Cyclopropanation of Enones
Ramig, Keith,Bhupathy, M.,Cohen, Theodore
, p. 4404 - 4412 (2007/10/02)
A new cyclopropanation procedure for α,β-unsaturated ketones is based upon the low-temperature decomposition of enolate carbenoids generated by conjugate addition of tris(phenylthio)methyllithium to α,β-unsaturated ketones followed by lithium/phenylthio e
Formation and Uses of the Dianion Formally Produced by Conjugate Addition of Bis(phenylthio)methyl Dianion to Cyclohex-2-en-1-one. Configurations and Conformations of the Products of Conjugate Addition of Tris(phenylthio)methyllithium to Carvone.
Cohen, Theodore,Yu, Lin-Chen
, p. 3266 - 3269 (2007/10/02)
When the enolate anion formed by the addition of tris(phenylthio)methyllithium to 2-cyclohexen-1-one is treated at -50 deg C with sec-butyllithium, the enolate thioacetal dianion 3 is generated.The latter forms useful compounds by the attack of electrophi
