97369-64-7Relevant academic research and scientific papers
Highly Electron-Deficient Pyridinium-Nitrones for Rapid and Tunable Inverse-Electron-Demand Strain-Promoted Alkyne-Nitrone Cycloaddition
Gunawardene, Praveen N.,Luo, Wilson,Polgar, Alexander M.,Corrigan, John F.,Workentin, Mark S.
, p. 5547 - 5551 (2019)
Highly accelerated inverse-electron-demand strain-promoted alkyne-nitrone cycloaddition (IED SPANC) between a stable cyclooctyne (bicyclo[6.1.0]nonyne (BCN)) and nitrones delocalized into a Cα-pyridinium functionality is reported, with the most
Hetero-Cope Rearrangements, III. - Vinylindoles via Hetero-Cope Rearrangement
Blechert, Siegfried
, p. 673 - 682 (2007/10/02)
The reaction of N-phenylnitrones 1 with allenes 2 which are substituted with electron acceptor groups gives various products via addition and sigmatropic rearrangement depending on the specific acceptor group.In this manner one obtains 2-substituted indoles 8a, 8b, and 10 from propadienyl trichloromethyl sulfoxide.Using phenyl propadienyl sulfone a derivative 4a of tetrahydro-1-benzazepin-4-one is obtained.Reactions with allenecarbonitril proceed via several steps and yield 2-vinylindoles of type 6.Intermediate products could not be isolated.
