97382-58-6Relevant academic research and scientific papers
One-Pot Conversion of Allylic Alcohols to α-Methyl Ketones via Iron-Catalyzed Isomerization-Methylation
Latham, Daniel E.,Polidano, Kurt,Williams, Jonathan M. J.,Morrill, Louis C.
, p. 7914 - 7918 (2019)
A one-pot iron-catalyzed conversion of allylic alcohols to α-methyl ketones has been developed. This isomerization-methylation strategy utilized a (cyclopentadienone)iron(0) carbonyl complex as precatalyst and methanol as the C1 source. A diverse range of allylic alcohols undergoes isomerization-methylation to form α-methyl ketones in good isolated yields (up to 84% isolated yield).
SODIUM SULFIDE AS A SELECTIVE REDUCING REAGENT FOR ALDEHYDES TO ALCOHOLS. USE OF ALUMINA AS AN EFFECTIVE CATALYST
Kamitori, Yasuhiro,Hojo, Masaru,Masuda, Ryoichi,Yamamoto, Masaki
, p. 253 - 254 (2007/10/02)
Intrinsic reactivity of sodium sulfide is well controlled by impregnating it on alumina, so that aldehydes can be readily reduced to the corresponding alcohols, while ketones, esters and even nitro compounds are all inert toward this reagent.
