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Deprotonation and Anionic Rearrangements of Organometallic Compounds. Reactions of the Hydride Complex (η5-C5H5)Re(NO)(PPh3)(H) with n-Butyl-lithium-Tetramethylethylenediamine
Crocco, Guy L.,Gladysz, J. A.
, p. 283 - 284 (1985)
The title reaction (-71 deg C; 1 h) gives (η5-C5H4Li)Re(NO)(PPh3)(H) (8), which subsequently rearranges intramolecularly (-32 deg C; 0.5 h) to give Li(1+)5-C5H5)Re(NO)(PPh3)>(1-) (3); the anions (8) and (3) are characterized by re
