97451-64-4

Upstream product

• 86650-76-2 ethyl (E)-3-methyl-6-(2,3,3-trimethyl-1-cyclopenten-1-yl)-4-hexanoate 
• 86650-75-1 (E)-1-(2,3,3-trimethyl-1-cyclopenten-1-yl)-3-penten-2-ole 
• 86650-74-0 (E)-1-(2,3,3-trimethyl-1-cyclopenten-1-yl)-3-penten-2-one 
• 1727-76-0 β-campholenonitrile 
• 13559-66-5 (+/-)-camphor oxime 
• 98-59-9 p-toluenesulfonyl chloride 
• 86650-77-3 (E)-3-methyl-6-(2,3,3-trimethyl-1-cyclopenten-1-yl)-4-hexen-1-ol 

Relevant academic research and scientific papers

INSECT GROWTH REGULATORS. PART XV. SYNTHESES OF JUVENOIDS WITH THE 2,3,3-TRIMETHYL-1-CYCLOPENTENE SYSTEM

New analogs of insect juvenile hormone were obtained by a multi-step synthesis starting from β-campholenenitrile (2).The Grignard reaction and the Claisen rearrangement by the orthoacetate method were applied for building and elongating an aliphatic chain.All compounds obtained are characterized by the presence of trans-disubstituted double bonds in the β-position in relation to the cyclopentane ring.