97507-59-0

Upstream product

• 103869-90-5 (E)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime 
• 103869-96-1 (Z)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime 
• 546-67-8 lead(IV) tetraacetate 
• 97507-47-6 5,5-dimethyl-1,3-bis(phenylhydrazono)-2-(p-tolylhydrazono)cyclohexane 
• 103869-95-0 C₁₆H₁₉N₃O₃ 
• 70820-93-8 5,5-dimethyl-cyclohexane-1,2,3-trione-1,3-dioxime-2-phenylhydrazone 
• 931385-21-6 N-(5,5-dimethyl-3-oxocyclohexenyl)-S,S-diphenylsulfilimine 
• 62-53-3 aniline 
• 103869-93-8 2-hydroximino-5,5-dimethyl-3-(phenylhydrazono)cyclohexanone 
• 126-81-8 dimedone 
• 2703-74-4 1,1-dimethyl-3,4,5-cyclohexanetrione-4-oxime 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 

Downstream Products

• 103869-90-5 (E)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime 
• 103869-96-1 (Z)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime 
• 106446-25-7 4-(p-chlorophenylhydrazono)-6,6-dimethyl-2-phenyl-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazole 
• 97507-65-8 6,6-dimethyl-4-(p-nitrophenylhydrazono)-2-phenyl-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazole 
• 106446-24-6 6,6-dimethyl-2-phenyl-4-(p-tolylhydrazono)-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazole 
• 128501-71-3 4,6,7,8-tetrahydro-7,7-dimethyl-2-phenyl-5H-1,2,3-triazol<4,5-c>azepine 
• 128501-68-8 5,6,7,8-tetrahydro-7,7-dimethyl-2-phenyl-1,2,3-triazol<4,5-c>azepin-4-one 
• 128501-72-4 5-acetyl-5,6,7,8-tetrahydro-7,7-dimethyl-2-phenyl-1,2,3-triazol<4,5-c>azepin-4-one 
• 128501-75-7 (Z)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime p-toluenesulfonate 
• 128501-76-8 (E)-4,5,6,7-tetrahydro-6,6-dimethyl-2-phenyl-2H-benzo<1,2,3>triazol-4-one oxime p-toluenesulfonate 

Relevant academic research and scientific papers

Formation of 1,2,5-oxadiazole, isoxazole, isothiazole, 1,2,3-triazole, and pyrrole rings from N-(5,5-dimethyl-3-oxocyclohexenyl)-S,S-diphenylsulfilimine

Reactions of N -(5,5-dimethyl-3-oxocyclohexenyl)- S,S -diphenylsulfilimine, a kind of enaminone, with isopentyl nitrite, isocyanates, isothocyanates, benzenediazonium chloride, and 1,1,1-trifluoro-4-ethoxy-3-buten-2-one gave 1,2,5-oxadiazole, isoxazole, i

Conversion of bicyclic C-azoaziridines to 2-substituted 2H-1,2,3-triazoles

In an acidified chloroform solution, bicyclic C-azo-N-(N-hetaryl)aziridines are converted to bicyclic 2H-1,2,3-triazoles. This transformation can occur on the surface of silica gel, and also during storage of these compounds at room temperature. 2005 Spri

BECKMANN REARRANGEMENT OF (Z)- AND (E)-OXIMES OF 2-ARYL-4,5,6,7-TETRAHYDRO-6,6-DIMETHYL-2H-BENZOTRIAZOL-4-ONES AND 4,5,6,7-TETRAHYDRO-6,6-DIMETHYLBENZOOXADIAZOL-4-ONES

The synthesis and geometry of (Z)- and (E)-oximes, II and III, derivatives of tetrahydro-2H-benzotriazoles and tetrahydrobenzooxadiazoles, was investigated.The possibility of structural assignments of II and III by Beckmann rearrangement was examined.Some CNDO/2 calculations were also carried out on the oximes II and III.

182. Heterocyclic Rearrangement of 4,5,6,7-Tetrahydro-6,6-dimethylbenzooxadiazol-4-one (Z)-Arylhydrazones into Corresponding 2-Aryl-4,5,6,7-tetrahydro-2H-benzotriazol-4-one Oximes

The thermal base-catalysed and photochemical transformation (Boulton-Katritzky rearrangement) of the title tetrahydrobenzooxadiazoles to tetrahydro-2H-benzotriazoles is studied.Attempts to induce analogous rearrangement in tetrahydro-2H-benzotriazol-4-one arylhydrazones or oximes failed.Some CNDO/2 calculations are also carried out.

Lead Tetra-acetate Oxidation of Tris(arylhydrazones) of Cyclohexane-1,2,3-triones

Oxidation of the title compounds with lead tetra-acetate gives 2-aryl-4-arylhydrazono-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazoles, the corresponding 4-oxo-derivatives, and as minor products 2-aryl-4-acetoxy-4-arylazo-4,5,6,7-tetrahydro-2H-benzo-1,2,3-triazoles, and substituted azobenzenes.The oxidation mechanism is discussed.