97509-98-3Relevant academic research and scientific papers
Photoreduction d'esters d'acides perfluores dans l'hexamethylphosphortriamide (HMPT). Elimination selective du fluor en α du groupe carboxyle
Portella, C.,Pete, J. P.
, p. 211 - 214 (1985)
The first example of fluorine elimination α to a carboxyl group is reported.The defluorination occurs when solution of perfluorocarboxylic esters in hexamethylphosphortriamide are irradiated with UV light (254 nm).Mechanistic and synthetic aspects of this new reaction are described.
