Tetrahedron Letters p. 211 - 214 (1985)
Update date:2022-08-04
Topics:
Portella, C.
Pete, J. P.
The first example of fluorine elimination α to a carboxyl group is reported.The defluorination occurs when solution of perfluorocarboxylic esters in hexamethylphosphortriamide are irradiated with UV light (254 nm).Mechanistic and synthetic aspects of this new reaction are described.
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Doi:10.1016/0022-328X(85)87140-0
(1985)Doi:10.1246/bcsj.58.793
(2021)Doi:10.1002/ardp.19853180503
(1985)Doi:10.1021/jo01029a073
(1964)Doi:10.1021/ja01644a053
(1954)Doi:10.1016/0006-3002(52)90066-8
(1952)
