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α-Allyl-α-benzoyldithioacetate is a chemical compound with the molecular formula C13H14O2S2. It is a derivative of dithioacetate, featuring an allyl group and a benzoyl group attached to the α-carbon. This organic compound is known for its potential applications in organic synthesis, particularly as a protecting group in the formation of carbon-sulfur bonds. It can also be used in the synthesis of various pharmaceuticals and agrochemicals due to its reactivity and stability. The compound's structure allows for selective reactions and controlled release of the protected functional groups, making it a valuable tool in the field of chemistry.

97510-22-0

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97510-22-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 97510-22-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,7,5,1 and 0 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 97510-22:
(7*9)+(6*7)+(5*5)+(4*1)+(3*0)+(2*2)+(1*2)=140
140 % 10 = 0
So 97510-22-0 is a valid CAS Registry Number.

97510-22-0Relevant academic research and scientific papers

Indium(0)-mediated Csp 3-S/O cross-coupling approach towards the regioselective alkylation of α-enolic esters/dithioesters: A mechanistic Insight

Chowdhury, Sushobhan,Chanda, Tanmoy,Gupta, Ashutosh,Koley, Suvajit,Ramulu, B. Janaki,Jones, Raymond C. F.,Singh, Maya Shankar

supporting information, p. 2964 - 2971 (2014/05/20)

We have reported an indium(0)-mediated Csp3-S/O cross-coupling approach that leads to the highly regioselective alkylation of α-enolic acetate/dithioacetate systems. This hetero cross-coupling reaction does not require additional co-catalyst or promoter, and the in situ generated organoindium species promotes the reaction by acting as the coupling partner of the α-enolic acetate/dithioacetate substrates. The excellent selectivity for C-, S-, or O-alkylation is solely dependent on the nucleophilic behavior of α-enolic acetate/dithioacetate systems. These results were further supported by DFT calculations of the relative electronic energies of the substrates and products as well as the activation barriers of the respective transformations.

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