97531-38-9Relevant academic research and scientific papers
Transition metal-free and regioselective vinylation of phosphine oxides and: H -phosphinates with VBX reagents
Castoldi, Laura,Rajkiewicz, Adam A.,Olofsson, Berit
, p. 14389 - 14392 (2020/12/01)
A series of phosphine oxides and H-phosphinates were vinylated in the presence of the iodine(iii) reagents vinylbenziodoxolones (VBX), providing the corresponding alk-1-enyl phosphine oxides and alk-1-enyl phosphinates in good yields with complete chemo- and regioselectivity. The vinylation proceeds in open flask under mild and transition metal-free conditions.
Iridium-N,P-ligand-catalyzed enantioselective hydrogenation of diphenylvinylphosphine oxides and vinylphosphonates
Cheruku, Pradeep,Paptchikhine, Alexander,Church, Tamara L.,Andersson, Pher G.
supporting information; experimental part, p. 8285 - 8289 (2009/12/02)
Diphenylvinylphosphine oxides and di- and trisubstituted vinylphosphonates have been employed as substrates in iridium-catalyzed asymmetric hydrogenations. Complete conversions and excellent enantioselectivities (up to and above 99percent ee) were observe
