97551-44-5

Upstream product

• 696-28-6 dichlorophenylarsine 
• 4451-96-1 diphenyl(trimethylsilylmethyl)phosphane 

Downstream Products

• 127666-22-2 Au2Cl2(μ-bis(diphenylphosphinomethyl)phenylarsine) 
• 127666-24-4 C₃₂H₂₉AsAu₃Cl₃P₂ 
• 100082-61-9 Rh₃((C₆H₅)2PCH₂As(C₆H₅)CH₂P(C₆H₅)2)2(CO)3Cl₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=Rh₃((C₆H₅)2PCH₂As(C₆H₅)CH₂P(C₆H₅)2)2(CO)3Cl₂B(C₆H₅)4 

Relevant academic research and scientific papers

Rearrangement and redistribution reaction of Ph2PCH2TMS with PhAsCl2 or AsCl3

The attempted synthesis of bis(diphenylphosphinomethyl) phenylarsane and tris(diphenylphosphinomethyl) arsane through condensation of chloro arsanes and diphenyl (trimethylsilylmethyl) phosphane yielded a number of side products originating from migratory and redox-reactions in addition to the targeted ligands. An unexpected, 1,3,4-phosphadiarssolan-1-ium salt was obtained and crystallographically characterized as an A-shaped chlorido adduct.