97576-82-4

Upstream product

• 65827-59-0 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl chloride 
• 97576-68-6 (2S,3S,4R,5R,6R)-2-Allyloxy-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-ol 
• 189324-22-9 (3aS,5R,6R,7S,7aS)-2-Allyloxy-6,7-bis-benzyloxy-5-benzyloxymethyl-2-methyl-tetrahydro-[1,3]dioxolo[4,5-b]pyran 
• 108869-64-3 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate 
• 79317-18-3 1-O-allyl-2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 79218-68-1 ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 16697-49-7 3,4,6-tri-O-benzyl-1,2-O-(methoxyethylidene)-β-D-mannopyranose 

Downstream Products

• 97576-74-4 allyl (3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 324041-20-5 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1-> 2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate 
• 425387-58-2 allyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->3)-2-O-acetyl-α-D-mannopyranoside 
• 405111-56-0 allyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->3)-4,6-O-benzylidene-α-D-mannopyranoside 
• 425387-57-1 allyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->3)-2-O-acetyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 97576-77-7 3,4,6-tri-O-benzyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranosyl chloride 
• 97576-83-5 allyl 3,4,6-tri-O-benzyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 97576-84-6 3,4,6-tri-O-benzyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranose 

Relevant academic research and scientific papers

Intramolecular aglycon delivery for (1 → 2)-β-mannosylation: Towards the synthesis of phospholipomannan of Candida albicans

A high yielding method for 1,2-cis-β-D-mannosylation by intra-molecular aglycon delivery (IAD) through p-methoxy benzyl ether/acetal exchange and phenylsulfoxide donor is reported, along with its application in iterative assembly of antigenic (1 → 2)-β-pe

Syntheses of oligomannosides in solution and on a soluble polymer support: A comparison

The α-(1→6)-linked and the α-(1→2)-linked linear mannotetraose glycosides 3 and 4, respectively, and the branched mannopentaoside 2 [R = CH2(CH2)2CH2Cl] were synthesised by conventional methods in solution, usin

A facile regio- and stereoselective synthesis of mannose octasaccharide of the N-glycan in human CD2 and mannose hexasaccharide antigenic factor 13b

A highly concise and effective synthesis of the mannose octasaccharide of the N-linked glycan in the adhesion domain of human CD2 was achieved via TMSOTf-promoted selective 6-glycosylation of a trisaccharide 4,6-diol acceptor with a pentasaccharide donor, followed by deprotection. The pentasaccharide was constructed by selective 3,6-diglycosylation of 1,2-O-ethylidene-β-D-mannopyranose with 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1 → 2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate, while the trisaccharide was obtained by selective 3-O-glycosylation of allyl 4,6-O-benzylidene-α-D-mannopyranoside with the same disaccharide trichloroacetimidate, followed by debenzylidenation. The mannose hexasaccharide antigenic factor 13b was synthesized by condensation of a trisaccharide donor, 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1 → 2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1 → 3)-4,6-di-O-acetyl-2-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate, with a trisaccharide acceptor, methyl 3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1 → 2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1 → 2)-3,4,6-tri-O-benzoyl-α-D-mannopyranoside, followed by deprotection.

SYNTHESIS OF A BRANCHED MANNOHEXAOSIDE, A PART STRUCTURE OF A HIGH-MANNOSE-TYPE GLYCAN OF A GLYCOPROTEIN

The synthesis is described of a branched mannohexaoside derivative, propyl 6-O--α-D-mannopyranoside, which corresponds to the non-reducing-end part-structure of a high-mannose-type g